Liliana Vess

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A Planeswalker from Magic: The Gathering, specializing in Black magic. Notable for being equal parts awesome, sexy, crazy, and power-hungry. Some demons own bits of her soul and she's trying to get them back. Also she has a thing called the Chain Veil which is a powerful artefact that'll corrupt your shit. Is (still?) being chased by Garruk who is giant and pissed off and really wants to cut her head off for getting icky evil black mana all up in his swoleness.

Faust

Liliana sold her soul to FOUR separate demons for power and eternal youth. Naturally, she is trying to get out of the contracts by killing said demons. So far, 2 down, 2 to go.

Griselbrand

Liliana broke open the Helvault to free Griselbrand so she could kill him (and then she killed him). A side effect was freeing the angel Avacyn, who was trapped in the Helvault.

Kothophed

Liliana's pact with Kothophed was for eternal youth. This was the last demon Liliana made a pact with and the first she offed. Liliana's tattoos are actually Kothophed's doing, as a way to keep her in line. It didn't work well enough to keep her from killing him.

Planeswalkers of Magic: The Gathering
Original Five:	Ajani Goldmane - Chandra Nalaar Garruk Wildspeaker - Jace Beleren - Liliana Vess
Alara:	Elspeth Tirel - Nicol Bolas - Sarkhan Vol - Tezzeret
Zendikar:	Gideon Jura - Nissa Revane - Sorin Markov
Scars of Mirrodin:	Karn - Koth of the Hammer - Venser
Innistrad:	Tamiyo - Tibalt - Davriel Cane
Return to Ravnica:	Domri Rade - Ral Zarek - Vraska
Theros:	Ashiok - Kiora - Xenagos - Calix
Tarkir:	Ugin - Narset
Kaladesh:	Dovin Baan - Saheeli Rai
Amonkhet:	Samut
Other:	Dack Fayden - Vivien Reid - Kaya
Commander 2014:	Daretti - Freyalise - Nahiri - Ob Nixilis - Teferi
Pre-mending:	Bo Levar - Commodore Guff - Jaya Ballard - Urza
Forgotten Realms:	Ellywick Tumblestrum - Bahamut - Lolth - Zariel - Mordenkainen
Planeswalker Groups:	The Gatewatch