Horus
Horus was the main figure in the event known as the Horus Heresy (this is NOT a dead giveaway. Oh no) in which he, yeah you guessed it, betrays his father of sorts - the Emperor and turns to Chaos. Before that he was the Primarch most favored by the Em--oh come on! If you really need to be told any of this, what the fuck are you doing on /tg/ in the first place?
Horus was weak, Horus was a fool. He had the galaxy in the palm of his hand, and let it slip away. - Abaddon.(By the way Abbadon is a total fuckin' douche bag. He can't take a fucking planet and calls Horus a failure even thought Horus managed to turn the Emprah into a fuckin' vegatable who sits on an overated toilet. Pretty fuckin' ironic huh?)